Complexes of Palladium(II) and Platinum(II) with 2-Aminomethylpyridine (2-Picolylamine)
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چکیده
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Structure and Chromotropic Properties of 2-Picolylamine-Ni(II) Complex
A symmetric complex [NiL2(H2O)2]Cl2, where L = 2-picolylamine was synthesized and characterized by spectroscopic and structural methods. Single crystal X-ray studies reveal that the Ni(II) center located in a pseudo-octahedral N4O2 environment with bidentate ligands L positioned in basal and two water molecules in the apical position. The complex is solvatochromic, ionochromic and thermochromic...
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we have recently synthesized ti(bh4)3(thf)3 and v(bh4)2(tmeda)2 complexes. the reaction of ticl3(thf)3 with nabh4 in dry thf gave flat blue crystals, ti(bh4)3(thf)3. the reaction of vcl3 with nabh4 in presence of n, n, n', n'- tetramethylethylenediamine, tmeda, produced violet crystals, v(bh4)2(tmeda)2. vibrational and magnetic properties of ti(bh4)3(thf)3 and v(bh4)2(tmeda)2 have been studied.
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ژورنال
عنوان ژورنال: Australian Journal of Chemistry
سال: 1962
ISSN: 0004-9425
DOI: 10.1071/ch9620563